Methyl 3,5-bis[(4-hydroxymethyl-2-methoxyphenoxy)methyl]benzoate
نویسندگان
چکیده
In the title compound, C(26)H(28)O(8), the central aromatic ring forms dihedral angles of 24.32 (11) and 80.19 (7)° with the two adjoining vanillyl alcohol rings. In the crystal, O-H⋯O hydrogen bonds connect the mol-ecules, forming a hydrogen-bonded sheet-like motif extended in the ab plane.
منابع مشابه
catena-Poly[[diaquabis{μ2-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate]
In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxyl-ate O atoms from two different 3,5-bis-(pyridin-4-yl-methyl-amino)-benzoate anions, two O atoms from two coordinated water mol-ecules and two N atoms from two different 3,5-bis-(pyridin-4-yl-methyl-amino)-benzoate anions, displa...
متن کاملBis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN 3}bis(3,5-dicarboxybenzoato-κO 1)zinc octahydrate
In the title complex, [Zn(C(9)H(5)O(6))(2)(C(11)H(10)N(4))(2)]·8H(2)O, the Zn(II) ion exhibits site symmetry 2. It shows a distorted tetra-hedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imid-azole ligands and by two O atoms from two symmetry-related monodeprotonated 3,5-dicarb-oxy-benzoate anions. In the crystal, complex mol-ecules and ...
متن کاملBis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN 3}bis(3,5-dicarboxybenzoato-κ2 O 1,O 1′)nickel(II) octahydrate
In the title complex, [Ni(C9H5O6)2(C11H10N4)2]·8H2O, the Ni(II) ion exhibits site symmetry 2. It has a distorted octa-hedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-1-yl)meth-yl]-1H-imidazole ligands and four O atoms from two symmetry-related 3,5-dicarb-oxy-benzoate anions. In the crystal, the complex mol-ecules and solvent water mol-ecules are linked v...
متن کاملBis{μ-(E)-methyl 4-[(2-carbamothioylhydrazinylidene)methyl]benzoate-κ2 S:S}bis[iodido(triphenylphosphane-κP)copper(I)]
The title complex, [Cu(2)I(2)(C(10)H(11)N(3)O(2)S)(2)(C(18)H(15)P)(2)], is a centrosymmetric sulfur-bridged dimer of Cu(I) with PPh(3) and iodine. The Cu(I) atom shows a distorted tetra-hedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intra-molecular Cu⋯Cu distance is 2.8228 (12) Å. The thio-semicarbazone ligand is coordinated only through the S atom. In the crystal,...
متن کاملThe co-crystal N,N′-bis[(pyridin-1-ium-2-yl)methyl]ethanedithioamide bis(2,6-dinitrobenzoate)–2,6-dinitrobenzoic acid (1/4)
The asymmetric unit of title co-crystal, C14H16N4S2 (2+)·2C7H3N2O6 (-)·4C7H4N2O6, comprises a centrosymmetric dipyridinium dication, a 2,6-di-nitro-benzoate anion and two independent 2,6-di-nitro-benzoic acid mol-ecules. The pyridin-ium rings are each approximately perpendicular to the central di-thio-amide unit [dihedral angle = 80.67 (12)°]. The carboxyl-ate/carb-oxy-lic acid groups are appro...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010